Section 1 - Identification Of Chemical Product And Company

Rentokil Initial Pty Ltd 150 Mowbray Rd Willoughby NSW 2068 ABN 98 000 034 597

Telephone (02)9370 9300 Fax (02)9958 6711

Substance: Complex mixture of fragrance ingredients (see below).

Trade Name: SUMMER SUNSHINE 83

Product Use: Perfume compound.

Creation Date: November, 2004

Revision Date: November, 2004

Section 2 - Hazards Identification

Statement of Hazardous Nature

This product is classified as: Hazardous according to the criteria of NOHSC Australia.

Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.

Risk Phrases: R43, R65, R52/53. May cause sensitisation by skin contact. Harmful: May cause lung damage if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects to the aquatic environment.

Safety Phrases: S24, S28, S46, S62, S37/39. Avoid contact with skin. After contact with skin, wash immediately with plenty of soap and water. If swallowed, contact a doctor or Poisons Information Centre immediately and show this container or label. If swallowed, do not induce vomiting: seek medical advice immediately and show this MSDS. Wear suitable gloves and eye/face protection.

SUSDP Classification: None allocated.

ADG Classification: None allocated. Not a Dangerous Good.

UN Number: None allocated

Emergency Overview

Physical Description & colour: Yellow liquid.

Odour: "Oriental" odour with vanilla, floral and citrus-like notes.

Major Health Hazards: possible skin sensitiser, if aspirated, may cause lung damage.

Potential Health Effects

Inhalation

Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this product is not harmful. In addition product is unlikely to cause any discomfort or irritation.

Long Term exposure: No data for health effects associated with long term inhalation.

Skin Contact:

Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can be severe. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Long Term exposure: No data for health effects associated with long term skin exposure.

Eye Contact:

Short term exposure: Exposure via eyes is considered to be unlikely. This product may cause eye irritation when present at high vapour pressures; for example when heated or in enclosed spaces. In addition product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort.

Long Term exposure: No data for health effects associated with long term eye exposure.

Ingestion:

Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. This product is unlikely to cause any irritation problems in the short or long term.

Long Term exposure: No data for health effects associated with long term ingestion.

Carcinogen Status:

NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.

NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: No significant ingredient is classified as carcinogenic by IARC.

Section 3 - Composition/Information on Ingredients

Ingredients CAS No Conc,% TWA (mg/m³) STEL (mg/m³)

Complex mixture of fragrance ingredients various * 100 not set not set

* Includes the following ingredients: CAS Percent range

Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl- 76-22-2 5% - 10%

Terpineol 8000-41-7 1% - 5%

2-Propenal, 2-hexyl-3-phenyl- 101-86-0 1% - 5%

2H-1-Benzopyran-2-one 91-64-5 1% - 5%

2'-Acetophenone, 5'6'7'8'-tetrahydro-3'5'5'6'8'8'-hexamethyl 21145-77-7 1% - 5%

2H-Pyran-4-ol, tetrahydro-3-pentyl-, acetate 18871-14-2 1% - 5%

6-Octen-1-ol, 3,7-dimethyl- 106-22-9 1% - 5%

Bicyclo[3.1.1]heptane, 6,6-dimethyl-2-methylene- 127-91-3 0.1 - 1%

Benzenepropanal, ..-methyl-4-(1-methylethyl)- 103-95-7 0.1 - 1%

Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl- 80-56-8 0.1 - 1%

Phenol, 5-methyl-2-(1-methylethyl)- 89-83-8 0.1 - 1%

The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

Section 4 - First Aid Measures

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call.

Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Skin Contact: If poisoning occurs, contact a Poisons Information Centre, or call a doctor at once. Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed. If in doubt obtain medical advice.

Eye Contact: Flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelid(s) open. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.

Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.

Section 5 - Fire Fighting Measures

Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is a slight risk of an explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam. Avoid the use of water jets.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.

Flash point: 70°C, Luchaire closed cup

Upper Flammability Limit: No data.

Lower Flammability Limit: No data.

Autoignition temperature: No data.

Flammability Class: C1

Section 6 - Accidental Release Measures

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective clothing including eye/face protection. All skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include PVC, Viton. Eye/face protective equipment should comprise as a minimum, protective glasses and, preferably, goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8).

Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Can be slippery on floors, especially when wet. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

Exothermic reactions leading to spontaneous combustion are possible when products of this type are absorbed onto porous materials such as zeolites, other mineral derived products, and even rags. Therefore, avoid the use of those materials and seek specialist advice in large scale cleanup processes.

Section 7 - Handling and Storage

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.

Storage: Note that this product is combustible and therefore, for Storage, may meet the definition of Dangerous Goods in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's Dangerous Goods laws in order to clarify your obligations regarding their storage.

Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Check packaging - there may be further storage instructions on the label.

Section 8 - Exposure Controls and Personal Protection

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

Exposure Limits TWA (mg/m³) STEL (mg/m³)

Exposure limits have not been established by NOHSC for this product.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that vapours and mists are minimised.

Eye Protection: Eye protection such as protective glasses or goggles should be worn when there is a chance of irritant levels of vapours being generated. However, it would be better to remove the vapours or avoid their generation.

Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.

Protective Material Types: We suggest that protective clothing be made from the following materials: PVC, nitrile.

Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above.

Safety deluge showers should be provided near to where this product is being used.

Section 9 - Physical and Chemical Properties:

Physical Description & colour: Yellow liquid.

Odour: "Oriental" odour with vanilla, floral and citrus-like notes.

Boiling Point: Not available.

Freezing/Melting Point: No specific data. Liquid at normal temperatures.

Volatiles: No data.

Vapour Pressure: 0.057 kPa at 20°C

Vapour Density: No data.

Specific Gravity: 0.926 at 20/20°C

Water Solubility: No data. Expected to be largely insoluble.

pH: No data.

Volatility: No data.

Odour Threshold: No data.

Evaporation Rate: No data.

Coeff Oil/water distribution: No data

Autoignition temp: No data.

Section 10 - Stability and Reactivity

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.

See Section 6 of this MSDS regarding reactivity with porous materials and rags.

Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.

Incompatibilities: oxidising agents, porous materials such as zeolites and similar mineral products, rags.

Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.

Polymerisation: Polymerisation reactions are unlikely; they are not expected to occur.

Section 11 - Toxicological Information

Local Effects:

Target Organs: There is no data to hand indicating any particular target organs.

Classification of Hazardous Ingredients

Ingredient Risk Phrases

No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous concentrations.

Section 12 - Ecological Information

Harmful to aquatic organisms, may cause long-term adverse effects to the aquatic environment. Insufficient data to be sure of status.

Section 13 - Disposal Considerations

Disposal: Containers should be emptied as completely as practical before disposal. If possible, recycle containers either in-house or send to recycle company. If this is not practical, send to a commercial waste disposal site. Please do NOT dispose into sewers or waterways.

Section 14 - Transport Information

ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary unless required by other regulations.

Section 15 - Regulatory Information

AICS: This product was found in the public AICS Database.

Section 16 - Other Information

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:

ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail

AICS Australian Inventory of Chemical Substances

CAS number Chemical Abstracts Service Registry Number

Hazchem Number Emergency action code of numbers and letters that provide information to emergency services especially firefighters

IARC International Agency for Research on Cancer

NOHSC National Occupational Health and Safety Commission

NOS Not otherwise specified

NTP National Toxicology Program (USA)

R-Phrase Risk Phrase

SUSDP Standard for the Uniform Scheduling of Drugs & Poisons

UN Number United Nations Number

THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.

IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS

OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the NOHSC document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)]
Copyright © Kilford & Kilford Pty Ltd, November, 2004.

http://www.kilford.com.au/ Phone (02)9251 4532